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Get Support › More ways to get help For general enquiries, send us a message or Call us between our operation hours 09:00 to 18:00 (Sunday to Saturday). Ensure that your contact details are correct in your Accounts Payable Settings. Amazon Payment Services Support Center Support center We’re always here for you! Find help and the advice you need. Managing your Amazon Business American Express Card Account Online. Amazon Payment Services Support Center>Amazon Payment Services Support Center. Here are the steps to pay your Amazon credit card bill by phone: Call Synchrony Bank at 866-634-8379. Amazon Store Card and Amazon Secured Card Promotional Financing; Make a Payment on an Amazon Store Card or Amazon Secured Card Account; Amazon Rewards Visa Signature Card Points; Amazon Credit Cards; Terms and Conditions for Payments from a Bank Account; Amazon. Contact Us and Customer Service Information. 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